Aluminium oxide

Aluminium oxide
Identifiers
CAS number	1344-28-1
Properties
Molar mass	101.96 g/mol
Density	3.97 g cm−3, solid
Melting point	2054 °C
Boiling point	2980 °C
Solubility in water	insoluble
Structure
Coordination geometry	octahedral
Thermochemistry
Std enthalpy of formation ΔfHo298	−1675.7 kJ mol−1
Standard molar entropy So298	50.92 J mol−1 K−1
Hazards
MSDS	External MSDS
EU classification	Not listed.
Flash point	non-flammable
Related compounds
Other anions	aluminium hydroxide
Other cations	boron trioxide gallium oxide indium oxide thallium oxide
Supplementary data page
Structure and properties	n, εr, etc.
Thermodynamic data	Phase behaviour Solid, liquid, gas
Spectral data	UV, IR, NMR, MS
Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa)
Infobox references

Aluminium oxide is an amphoteric oxide of aluminium with the chemical formula Al₂O₃. It is also commonly referred to as alumina or aloxite in the mining, ceramic and materials science communities. It is produced by the Bayer process from bauxite; its most significant use is in the production of aluminium metal. Being very hard, it is used as an abrasive. Having a high melting point, it is used as a refractory material.

Natural occurrence

Corundum is the naturally occurring crystalline form of aluminium oxide. Rubies and sapphires are gem-quality forms of corundum with their characteristic colors due to trace impurities in the corundum structure.

Properties

Aluminium oxide is an electrical insulator but has a relatively high thermal conductivity (40 W/m K). In its most commonly occurring crystalline form, called corundum or α-aluminium oxide, its hardness makes it suitable for use as an abrasive and as a component in cutting tools.

Aluminium oxide is responsible for metallic aluminium's resistance to weathering. Metallic aluminium is very reactive with atmospheric oxygen, and a thin passivation layer of alumina quickly forms on any exposed aluminium surface. This layer protects the metal from further oxidation. The thickness and properties of this oxide layer can be enhanced using a process called anodising. A number of alloys, such as aluminium bronzes, exploit this property by including a proportion of aluminium in the alloy to enhance corrosion resistance. The alumina generated by anodising is typically amorphous, but discharge assisted oxidation processes such as plasma electrolytic oxidation result in a significant proportion of crystalline alumina in the coating, enhancing its hardness.

Aluminium oxide was taken off the United States Environmental Protection Agency's chemicals lists in 1988. Aluminium oxide is on EPA's TRI list if it is a fibrous form.

Crystal structure

The most common form of crystalline alumina, α-aluminium oxide, is known as corundum. Corundum has a trigonal Bravais lattice with a space group of R-3c (number 167 in the International Tables). The oxygen ions nearly form a hexagonal close-packed structure with aluminium ions filling two-thirds of the octahedral interstices.

Production

Aluminium oxide, also known as alumina, is the main component of bauxite, the principal ore of aluminium. The largest manufacturers in the world of alumina are Alcoa, Alcan and Rusal. Companies which specialise in the production of speciality aluminium oxides and aluminium hydroxides include Alcan and Almatis. The bauxite ore is made up of impure Al₂O₃, Fe₂O₃, and SiO₂. Bauxite is purified by the Bayer process:

Al₂O₃ + 3 H₂O + 2 NaOH → 2NaAl(OH)₄

The Fe₂O₃ does not dissolve in the base. The SiO₂ dissolves as silicate Si(OH)₆^2-. Upon filtering, Fe₂O₃ is removed. When the Bayer liquor is cooled, Al(OH)₃ precipitates, leaving the silicates in solution. The mixture is then calcined (heated strongly) to give aluminium oxide:

2Al(OH)₃ + heat → Al₂O₃ + 3H₂O

The formed Al₂O₃ is alumina.

Uses

Annual world production of alumina is approximately 45 million tonnes, over 90% of which is used in the manufacture of aluminium metal.. The major uses of speciality aluminium oxides are in refractories, ceramics, polishing and abrasive applications. Large tonnages are also used in the manufacture of zeolites, coating titania pigments and as a fire retardant/smoke suppressant.

In lighting and photography, alumina is a medium for chromatography, available in basic ( pH 9.5), acidic (pH 4.5 when in water) and neutral formulations. In 1961, GE developed " Lucalox", a transparent alumina used in sodium vapor lamps. Aluminium oxide is also used in preparation of coating suspensions in compact fluorescent lamps.

Health and medical applications include it as a material in hip replacements, in water filters (derived water treatment chemicals such as aluminium sulfate, aluminium chlorohydrate and sodium aluminate, are one of the few methods available to filter water-soluble fluorides out of water), and even in toothpaste formulations.

Aluminium oxide is also used for its strength. Most pre- finished wood flooring now uses aluminium oxide as a hard protective coating. In 2004, 3M developed a technique for making a ceramic composed of aluminium oxide and rare earth elements to produce a strong glass called transparent alumina. Alumina can be grown as a coating on aluminium by anodising or by plasma electrolytic oxidation (see the "Properties" section, above). Both its strength and abrasive characteristics are due to aluminium oxide's great hardness (position 9 on the Mohs scale of mineral hardness).

It is widely used as a coarse or fine abrasive, including as a much less expensive substitute for industrial diamond. Many types of sandpaper use aluminium oxide crystals. In addition, its low heat retention and low specific heat make it widely used in grinding operations, particularly cutoff tools. As the powdery abrasive mineral aloxite, it is a major component, along with silica, of the cue tip "chalk" used in billiards. (See William A. Spinks, cue chalk co-inventor, for more information.) Aluminium oxide powder is used in some CD/DVD polishing and scratch-repair kits. Its polishing qualities are also behind its use in toothpaste.

Aluminium oxide is widely used in the fabrication of superconducting devices, particularly single electron transistors and superconducting quantum interference devices ( SQUID), where it is used to form highly resistive quantum tunnelling barriers.